Chemistry Journal of Moldova

TRINUCLEAR MIXED-VALENT MANGANESE COMPLEX WITH NON-SCHIFF-BASE TETRADENTATE LIGAND SHOWING A FERROMAGNETIC COUPLING

Author(s):

Masahiro Mikuriya, Iyo Matsushima, Daisuke Yoshioka


Field: Inorganic and coordination chemistry
Type: Research paper
Pages: 7
Keywords:

manganese complex, trinuclear complex, magnetic property, ferromagnetic interaction, mixed-valent complex.


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DOI: http://dx.doi.org/10.19261/cjm.2017.446   
 
Graphical Abstract: Mixed-valent trinuclear manganese complex with N,N’-bis(2-hydroxy-3,5-dimethylbenzyl-N,N’-dimethyl-1,2-ethanediamine (H2hdde), [Mn3(hdde)2(CH3CO2)2(CH3O)2], was synthesized.  The X-ray crystal structure analysis revealed a linearly arrangement of MnIII-MnII-MnIIIcore, where a ferromagnetic coupling (J = 2.62 cm–1) between the MnIII and MnII ions.


 

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