Chemistry Journal of Moldova

Accepted papers

Olena Litsis, Vladimir Ovchynnikov, Tatiana Sliva, Svitlana Shishkina, Vladimir Amirkhanov

Field: Inorganic and coordination chemistry
Type: Research paper
lanthanide, carbacylamidophosphate, phosphoryl ligand, six-coordinate lanthanide complex, electronic spectrum.
DOI: http://dx.doi.org/10.19261/cjm.2017.466   
 
Graphical Abstract: New mononuclear six-coordinate lanthanide coordination compounds [Ln (HL)3Cl3] (HL = (2,2,2-trichloro-N-(dipiperidin-1-yl-phosphoryl)acetamideCCl3C(O)N(H)P(O)[N(CH2)5]2, carbacylamidophosphate (CAPh) type ligand) have been synthesized from non-aqueous solutions. The complexes have been characterized by elemental analysis, spectroscopic methods (FTIR, 1H- and 31P-NMR, UV-Vis). The structure of [Sm(HL)3Cl3] has been further confirmed by single crystal X-ray diffraction analysis.

 
 

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Aculina Aricu, Lidia Lungu, Nadejda Tenu, Alexandru Ciocarlan, Yacob Gutu, Ion Dragalin, Alic Barba

Field: Organic chemistry
Type: Research paper
6
sesquiterpenoids, N-substituted amides, heterocyclic amines, diazine, 1,2,4-triazole, carbazole, synthesis.
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Graphical Abstract: The study describes the synthesis of 11-homodrim-6,8-dien-12-oic acid N-substituted amides containing diazine, 1,2,4-triazole and carbazole rings based on commercially available sclareolide. The mentioned compounds were prepared for the first time by interaction of the generated in situ acyl chloride with some heterocyclic amines: 2- and 4-aminopyrimidine, 2-aminopyrazine, 3-amino-1,2,4-triazole and N-aminocarbazole. Their structures were fully elucidated by elemental and spectral analyses (IR, 1H and 13C NMR).


 

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