Chemistry Journal of Moldova

THE USE OF SOME NON-CONVENTIONAL METHODS IN CHEMISTRY OF BICYCLOHOMOFARNESENIC METHYL ESTERS

Author(s):

Alexandru Ciocarlan, Lidia Lungu, Svetlana Blaja, Ion Dragalin, Aculina Aricu


Field: Natural product chemistry and synthesis
Type: Research paper
Issue: 2020 Volume 15, no.2
Pages: 69-77
Keywords:

bicyclohomofarnesenic methyl ester, microwave irradiation, anodic electrooxidation, dye-sensitized photooxidation.


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DOI: http://dx.doi.org/10.19261/cjm.2020.791

Abstract (PDF)
Graphical Abstract: The present paper reports the results of microwave irradiation assisted method for the preparation of bicyclohomofarnesenic methyl esters versus classical Stoll and Hinder method. Moreover, the chemical transformations of bicyclohomofarnesenic methyl esters via anodic electrooxidation and dye-sensitized photooxidation were performed. A new method for the preparation of methyl 7-oxo-13,14,15,16-tetranorlabd-6,8(8)-dien-12-oate and the mechanism of electrochemical products formation are presented. The structure of all synthesized compounds was fully confirmed by spectral methods.


 

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