Chemistry Journal of Moldova

THE THEORETICAL STUDY OF SOME REACTIONS WITH THE PARTICIPATION OF OH AND HO2 RADICALS

Author(s):

Ion Arsene


Field: Physical chemistry and chemical physics
Type: Research paper
Issue: 2008 Volume 3, no.2
Pages: 109-113
Keywords:

the radicals reactions, decomposition of hydrogen peroxide, the thermodynamic stability.


Full Text (PDF): Download

DOI:
dx.doi.org/10.19261/cjm.2008.03(2).18

Graphical Abstract:
 The geometry of the H2O2, OH, HO2, O2 particles and the energy profiles of the initial reactions between them, that are supposed to take place during the process of decomposition of hydrogen peroxide, were studied by ab initio calculations. It was shown that the differences between the energies of reactants and the products of all analysed reaction are positive values and correlate with the experimental data.


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