Chemistry Journal of Moldova

Industrial chemistry

Author(s):

Gh. Duca, A. Ivancic, V. Boldescu


Field: Industrial chemistry
Type: Review
Issue: 2012 Volume 7, no.2
Pages: 39-45
Keywords: cyclodextrins, pharmaceuticals, medicine, inclusion complexes.
Full Text (PDF): Download


Downloads: 23

Author(s):

Liudmila V. Dyakova, Aleksander G. Kasikov, Elena S. Kshumaneva, Svetlana V. Drogobuzhskaya


Field: Industrial chemistry
Type: Research paper
Issue: 2010 Volume 5, no.1
Pages: 90-94
Keywords: cobalt, solvent extraction, tertiary amines, salting-out, octanoic acid.
Full Text (PDF): Download

DOI:
dx.doi.org/10.19261/cjm.2010.05(1).08

Graphical Abstract: 
The paper deals with the extracting cobalt salts by using mixtures on the basis of tertiary amine from multicomponent solutions from the process of hydrochloride leaching of cobalt concentrate. The optimal composition for the extraction mixture, the relationship between the cobalt distribution coefficients and modifier’s nature and concentration, and the saltingout agent type have been determined. A hydrochloride extraction technology of cobalt concentrate yielding a purified concentrated cobalt solution for the production of pure cobalt salts has been developed and introduced at Severonikel combine.


Downloads: 19

Author(s):

Aleksander G. Kasikov, Anna M. Petrova


Field: Industrial chemistry
Type: Research paper
Issue: 2010 Volume 5, no.1
Pages: 95-97
Keywords: Rhenium, solvent extraction, long-chain aliphatic tertiary amine and alcohols, sulphuric acid media.
Full Text (PDF): Download

DOI:
dx.doi.org/10.19261/cjm.2010.05(1).09

Graphical Abstract:
 The effect of sulphuric acid concentration on solvent extraction of ReO4- by the long-chain aliphatic tertiary amines and alcohols in a wide range of H2SO4 concentrations in initial solutions is discussed. It has been established that the influence of the sulphuric acid concentration on rhenium solvent extraction is largely due to the extraction process mechanism. In the case of the anion-exchange mechanism, ReO4- is best extracted from weakly acidic solutions, whereas when the hydrate-solvate mechanism takes place – from solutions containing 4-7 mole/l H2SO4.


Downloads: 15

Author(s):

Gheorghe Duca, Veaceslav Boldescu


Field: Industrial chemistry
Type: Review
Issue: 2008 Volume 3, no.2
Pages: 30-37
Keywords: cyclodextrins, food, cosmetic industry, environmental protection, agriculture.
Full Text (PDF): Download

DOI:
dx.doi.org/10.19261/cjm.2008.03(2).12

Graphical Abstract:
 This review is dedicated to different fields of use of cyclodextrins, a family of three cyclic natural oligosaccharides and their derivatives. The first part of the review gives a brief description of the main and the most recent developed applications of cyclodextrins in food, cosmetic industry, environmental protection technologies and agriculture. Different products based on inclusion complexes with cyclodextrins and technologies with different use of cyclodextrins and inclusion complexes are described.


Downloads: 25

Author(s):

Veaceslav Boldescu,Irina Kacso, Ioan Bratub and Gheorghe Duca


Field: Industrial chemistry
Type: Research paper
Issue: 2008 Volume 3, no.1
Pages: 85-88
Keywords: sanguinarine, β-cyclodextrin, inclusion complex, UV-vis spectrophotometry, association constant.
Full Text (PDF): Download
Abstract (JPEG)

DOI:
dx.doi.org/10.19261/cjm.2008.03(1).18

Graphical Abstract:
The main aim of this study was to investigate the influence of pH and the presence of hydrophilic polymer polyvinylpyrrolidone on the formation of sanguinarine-β-cyclodextrin (SANG
-β-CD) inclusion complex. Spectrophotometric studies of the SANG-β-CD systems in the presence and without 0.1 % PVP at the pH 5.0 did not show any evidence of the complex formation. However, the same systems showed several obvious evidences at the pH 8.0: the hyperchromic and the hypochromic effects and the presence of the isosbestic point in the region of 200 –210 nm. The association constants calculated by three linear methods: Benesi-Hildebrand, Scott and Scatchard, were two times higher for the systems with addition of 0.1% PVP than for the systems without it.


Downloads: 19

Author(s):

Rodica Sturza


Field: Industrial chemistry
Type: Research paper
Issue: 2006 Volume 1, no.1
Pages: 65-72
Keywords: iodine deficiency, food fortification, iodinated sunflower oil.
Full Text (PDF): Download

DOI:
dx.doi.org/10.19261/cjm.2006.01(1).13

Graphical Abstract: 
The aim of this work is the study made for obtaining iodized oil that would satisfy the requirements in iodine for human body. The sunflower oil is a product with the most important value, thus the production of oil fortified with iodine would be a cheap and accessible option. These studies indicate that lipids present an important vehicle for the fortification with iodine. Eradication of the iodine deficiency may be realized not only by injection of the iodinated oil, but also by its use as an ingredient for the formulation of different food compositions. This method, complementary with the iodinated salt, would allow the increase of the efficiency of the prophylactic undertaken measures, because is based on the use of vegetal material – sunflower oil; it is cost-efficient and does not require substantial investments.


Downloads: 80