Chemistry Journal of Moldova

SYNTHESIS AND CRYSTAL STRUCTURES OF LUMINESCENT MONONUCLEAR Ni(II) AND Cd(II) COMPLEXES WITH 1,10-PHENANTHROLINE

Author(s):

Ecaterina Tocana, Anatolii Siminel, Lilia Croitor


Field: Supramolecular chemistry
Type: Research paper
Pages: 7
Keywords:

X-ray, 1,10-phenanthroline, supramolecular system, π–π stacking interaction, luminescence.


Full Text (PDF): Download
 
DOI: http://dx.doi.org/10.19261/cjm.2017.451   
 
Graphical Abstract: New supramolecular systems of Ni(II) and Cd(II) with 1,10-phenanthroline constructed by non-covalent interactions have been synthesized and characterized by single-crystal X-ray diffractometry. The smaller nickel(II) ion forms a cis complex with outer-sphere perchlorates, while the cadmium(II) ion forms a trans complex involving inner-sphere perchlorates. Both compoundsrevealintraligand-basedluminescentproperties.


Downloads: 17