ibn-ResPubl-45621
2016-06-22
11
1
33
1857-1727
https://ibn.idsi.md/ro/vizualizare_articol/45621
The formation mechanism of assembled complexes bridged by1,3–bis(4–pyridyl)propane
mixed crystal; assembled complex; 1; 3-bis(4-pyridyl)propane; crystal formation
Several types of differently coloured crystals (light blue, blue and red) were obtained in the synthesis of assembled complex of mixed crystals with three metals by using solvent diffusion method. The mechanism of obtaining the assembled complexes is discussed based on the structure and colour change. The red crystal has 2D interpenetrated structure. The light-blue samples were [H2(bpp)][M(NCS)4] and they were built up spirally. The blue samples were M(NCS)2(bpp) and they formed 1D chain. [H2(bpp)][M(NCS)4] changed to 1D chain polymer (M(NCS)2(bpp)) by releasing HNCS from the cation and anion in a reaction vessel. Inductively Coupled Plasma Atomic Emission Spectroscopy, Electrospray Ionization Mass Spectrometry and X-Ray diffraction were used for characterization of the obtained complexes.
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2016-06-22T24:00:00
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2016-06-22T24:00:00
ibn-person-48264
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2016-06-22T24:00:00
ibn-person-48265
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2016-06-22T24:00:00
ibn-person-48266
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2016-06-22T24:00:00
ibn-doi-45621
10.19261/cjm.2016.11(1).04
2016-06-22T24:00:00
31d222b4-11e0-434b-b5ae-088119c51189
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5123451
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ibn-Pers-48264
ibn-PersName-48264-3
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2016-06-22T24:00:00
Dote
Haruka
ibn-Pers-48265
ibn-PersName-48265-3
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2016-06-22T24:00:00
Yasuhara
Hiroki
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ibn-PersName-48266-3
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7375609d-cfa6-45ce-a803-75de69abe21f
2016-06-22T24:00:00
Nakashima
Satoru
5123451
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