Chemistry Journal of Moldova

RECENT STUDIES OF (+)-3-CARENE TRANSFORMATIONS WITH THE RETENTION OF THE NATIVE FRAMEWORK

Author(s):

Serghei Curlat


Field: Organic chemistry
Type: Review
Issue: 2019 Volume 14, no.2
Pages: 32-55
Keywords:

(+)-3-carene, epoxidation, sulphide, aminoalcohol, azidoalcohol, aziridine.


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DOI: http://dx.doi.org/10.19261/cjm.2019.616   
 
Abstract (PDF)
Graphical Abstract: This review presents last decade and some past especially relevant studies in the field of (+)-3-carene synthetic transformations. This paper discusses exclusively the transformations of (+)-3-carene, proceeding with the retention of the native bicyclic carbon skeleton. The data concerning the features of epoxidation and oxidation reactions of (+)-3-carene, the synthesis of sulphur- and selenium-containing derivatives and their use in asymmetric synthesis are given. It also describes methods for producing amino derivatives of (+)-3-carene, substituted heterocycles based on it, reactions for the preparation of aziridines, azido-alcohols and azidoamines, as well as chiral phosphites as bidentate ligands.


 

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