Chemistry Journal of Moldova

NOVEL IRON(II) AND COPPER(II) POLYMERIC COORDINATION COMPOUNDS WITH N,N′-BIPYRIDINE-TYPE LIGANDS: SYNTHESIS AND CHARACTERIZATION

Author(s):

Aliona Vitiu


Field: Supramolecular chemistry
Type: Research paper
Issue: 2019 Volume 14, no.1
Pages: 120-127
Keywords:

crystalline coordination polymer, bridging ligand, supramolecular system, π–π stacking interaction


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DOI: http://dx.doi.org/10.19261/cjm.2019.569   
 
Abstract (PDF)
Graphical Abstract: Two new 1D coordination polymers based on octahedral Fe(II) and square-pyramidal Cu(II) complexes and N,N'-bipyridine-type ligands were synthesized by slow evaporation method. The compounds with the formula {(bpyH2)•[Fe(bpy)2(H2O)2(SO4)2]•2(H2O)}n and {[Cu(bpp)2(H2O)]•(BF4)2•dmf•0.75(H2O)}n, (where bpy= 4,4'-bipyridine and bpp= 1,3-bis(4-pyridyl)propane, dmf= N,N-dimethylformamide) were characterized by thermal analysis, FT-IR spectroscopy and single crystal X-ray diffraction method.


 

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