Chemistry Journal of Moldova

NEW SOLVATOMORPH OF TETRAKIS(μ2-ACETATO-O,O')-BIS(ISONICOTINAMIDE-N)-DI-COPPER(II): SYNTHESIS, IR, TGA AND X-RAY STUDY

Author(s):

Diana Chisca, Eduard Coropceanu, Oleg Petuhov, Lilia Croitor


Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2015 Volume 10, no.2
Pages: 33-39
Keywords:

copper, isonicotinamide, X-ray, paddle-wheel structure.


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Abstract (PDF)

DOI:
dx.doi.org/10.19261/cjm.2015.10(2).03

Graphical Abstract:
 Dinucleartetracarboxylato-bridged copper(II)solvato-morph [Cu2(OAc)4(ina)2] •2dmso was prepared and studied by IR spectroscopy, TGA analysis and single crystal X-ray method. Cu(II) ions are bridged by four syn,syn-η1:η1:μ carboxylates, showing a paddle-wheel cage-type with a square-pyramidal geometry.


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