Chemistry Journal of Moldova

HOMOTRINUCLEAR Fe3III μ – OXO SALICYLATE CLUSTER. SYNTHESIS, STRUCTURE AND PROPERTIES

Author(s):

Viorina Gorinchoy, Sergiu Shova, Elena Melnic, Victor Kravtsov, ConstantinTurta


Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2013 Volume 8, no.2
Pages: 83-89
Keywords:

carboxy-cluster, Iron(III), salicylate, IR, Mössbauer, TG data


Full Text (PDF): Download

DOI:
dx.doi.org/10.19261/cjm.2013.08(2).10

Graphical Abstract:
A reaction of iron and barium nitrate with ammonium salicylate in the mixture of solvents leads to the formation of the new homotrinuclear complex, [Fe3O(SalH)7(H2O)2]∙(DMAA)2(MeOH)(THF)1,5(H2O)2,6. Single-crystal X-ray study shows that the titled complex with the moiety {Fe3O} belongs to the well-known group of μ3-oxohomotrinuclear carboxylates. The IR and MS studies are in accordance with x-ray data. Thermal behaviour of the complex was studied.

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