Chemistry Journal of Moldova

AZOLIGANDS AS BRIDGED IN MACROCYCLIC DINICKEL COMPLEXES

Author(s):

Vasile Lozan


Field: Inorganic and coordination chemistry
Type: Review
Issue: 2010 Volume 5, no.1
Pages: 7-23
Keywords:

coordination chemistry, structures, azoligands, nickel macrocyclic complexes, amino-thiophenolate ligands.


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Abstract (JPEG)

DOI:
dx.doi.org/10.19261/cjm.2010.05(1).01

Graphical Abstract:
 The coordination chemistry of dinickel macrocyclic hexaamine-dithiophenolate complexes of  Robson-type with azoligands is presented in this microreview. All complexes have been  characterised by IR-,UV/Visspectroscopy, and X-ray crystallography. The bioctahedral transition metal complexes of the type [(L6)Ni2(μ-L')]+ exhibit a rich coordination chemistry since the active coordination site L' is accessible for a wide range of exogenous coligands.

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